Interpretation of carbon dioxide diffusion behavior in coals   总被引：3，自引：1，他引：3  

Nikolai Siemons  Karl-Heinz A.A. Wolf  Johannes Bruining 《International Journal of Coal Geology》2007,72(3-4):315-324

Storage of carbon dioxide in geological formations is for many countries one of the options to reduce greenhouse gas emissions and thus to satisfy the Kyoto agreements. The CO₂ storage in unminable coal seams has the advantage that it stores CO₂ emissions from industrial processes and can be used to enhance coalbed methane recovery (CO₂-ECBM). For this purpose, the storage capacity of coal is an important reservoir parameter. While the amount of CO₂ sorption data on various natural coals has increased in recent years, only few measurements have been performed to estimate the rate of CO₂ sorption under reservoir conditions. An understanding of gas transport is crucial for processes associated with CO₂ injection, storage and enhanced coalbed methane (ECBM) production.A volumetric experimental set-up has been used to determine the rate of sorption of carbon dioxide in coal particles at various pressures and various grain size fractions. The pressure history during each pressure step was measured. The measurements are interpreted in terms of temperature relaxation and transport/sorption processes within the coal particles. The characteristic times of sorption increase with increasing pressure. No clear dependence of the characteristic time with respect to the particle size was found. At low pressures (below 1 MPa) fast gas diffusion is the prevailing mechanism for sorption, whereas at higher pressures, the slow diffusion process controls the gas uptake by the coal.  相似文献   

A new assessment of climate change impacts on food production shortfalls and water availability in Russia   总被引：2，自引：0，他引：2  

Joseph Alcamo  Nikolai Dronin  Marcel Endejan  Genady Golubev  Andrei Kirilenko 《Global Environmental Change》2007,17(3-4):429-444

While previous studies have focused on impacts of average climate change on Russian agriculture and water resources, this study takes into account the impact of changing frequency and spatial heterogeneity of extreme climate events, and the reliance of most of Russia on a few food producing regions. We analyze impacts of the IPCC A2 and B2 climate scenarios with the use of the Global Assessment of Security (GLASS) model (containing the Global Agro-Ecological Zones (GAEZ) crop production model and the Water-Global Assessment and Prognosis (WaterGAP 2) water resources model). As in previous studies we find that decreased crop production in some Russian regions can be compensated by increased production in others resulting in relatively small average changes. However, a different perspective on future risk to agriculture is gained by taking into account a change in frequency of extreme climate events. Under climate normal conditions it is estimated that “food production shortfalls” (a year in which potential production of the most important crops in a region is below 50% of its average climate normal production, taking into account production in food-exporting regions) occur roughly 1–3 years in each decade. This frequency will double in many of the main crop growing areas in the 2020s, and triple in the 2070s. The effects of these shortfalls are likely to propagate throughout Russia because of the higher likelihood of shortfalls occurring in many crop export regions in the same year, and because of the dependence of most Russian regions on food imports from a relatively few main crop growing regions. We estimate that approximately 50 million people currently live in regions that experience one or more shortfalls each decade. This number may grow to 82–139 million in the 2070s. The assessment of climate impacts on water resources indicates an increase in average water availability in Russia, but also a significantly increased frequency of high runoff events in much of central Russia, and more frequent low runoff events in the already dry crop growing regions in the South. These results suggest that the increasing frequency of extreme climate events will pose an increasing threat to the security of Russia's food system and water resources.  相似文献   

Lightning activity related to satellite and radar observations of a mesoscale convective system over Texas on 7–8 April 2002     

Nikolai Dotzek  Robert M. Rabin  Lawrence D. Carey  Donald R. MacGorman  Tracy L. McCormick  Nicholas W. Demetriades  Martin J. Murphy  Ronald L. Holle 《Atmospheric Research》2005,76(1-4):127

A multi-sensor study of the leading-line, trailing-stratiform (LLTS) mesoscale convective system (MCS) that developed over Texas in the afternoon of 7 April 2002 is presented. The analysis relies mainly on operationally available data sources such as GOES East satellite imagery, WSR-88D radar data and NLDN cloud-to-ground flash data. In addition, total lightning information in three dimensions from the LDAR II network in the Dallas–Ft. Worth region is used.GOES East satellite imagery revealed several ring-like cloud top structures with a diameter of about 100 km during MCS formation. The Throckmorton tornadic supercell, which had formed just ahead of the developing linear MCS, was characterized by a high CG+ percentage below a V-shaped cloud top overshoot north of the tornado swath. There were indications of the presence of a tilted electrical dipole in this storm. Also this supercell had low average CG− first stroke currents and flash multiplicities. Interestingly, especially the average CG+ flash multiplicity in the Throckmorton storm showed oscillations with an estimated period of about 15 min.Later on, in the mature LLTS MCS, the radar versus lightning activity comparison revealed two dominant discharge regions at the back of the convective leading edge and a gentle descent of the upper intracloud lightning region into the trailing stratiform region, apparently coupled to hydrometeor sedimentation. There was evidence for an inverted dipole in the stratiform region of the LLTS MCS, and CG+ flashes from the stratiform region had high first return stroke peak currents.  相似文献   

Self-reversal of remanent magnetization in basalts due to partially oxidized titanomagnetites     

David Krása  Valera P. Shcherbakov  Thomas Kunzmann  Nikolai Petersen 《Geophysical Journal International》2005,162(1):115-136

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Nonstationary Phenomena in the Solar Wind and InterstellarMedium Interaction     

Nikolai V. Pogorelov 《Astrophysics and Space Science》2000,274(1-2):115-122

We discuss the results of numerical modeling of the solar wind with the inhomogeneous interstellar medium. The density of the plasma component in the interstellar cloud is supposed to be space periodic. The interaction pattern is shown to be highly unsteady with hydrodynamic instabilities developing on the side portion of the heliopause. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Accretion Flows: Aspects of Gas Dynamic Modeling     

Nikolai V. Pogorelov  Igor A. Kryukov 《Astrophysics and Space Science》2000,274(1-2):275-284

We present our view on the application of numerical models to accretion flows in astrophysics. Special attention is paid to the problem of existence of steady-state solutions in time-dependent calculations and to origin of numerically induced instabilities. The problem is considered of the supersonic wind accretion onto gravitating objects. We also present the results of the gas dynamic simulation of accretion on a body imitating the shape of the star magnetosphere with holes in its polar regions. This shape can occur as a result of the cusp disintegration owing to theRayleigh–Taylor instability in the equatorial region of the magnetosphere. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Electrical conductivity of polycrystalline Mg(OH)<Subscript>2</Subscript> at 2 GPa: effect of grain boundary hydration–dehydration     

Julien Gasc  Fabrice Brunet  Nikolai Bagdassarov  Victor Morales-Flórez 《Physics and Chemistry of Minerals》2011,38(7):543-556

The effect of intergranular water on the conductivity of polycrystalline brucite, Mg(OH)₂, was investigated using impedance spectroscopy at 2 GPa, during consecutive heating–cooling cycles in the 298–980 K range. The grain boundary hydration levels tested here span water activities from around unity (wet conditions) down to 10⁻⁴ (dry conditions) depending on temperature. Four orders of magnitude in water activity result in electrical conductivity variations for about 6–7 orders of magnitude at 2 GPa and room temperature. Wet brucite samples containing, initially, about 18 wt% of evaporable water (i.e. totally removed at temperatures below 393 K in air), display electrical conductivity values above 10⁻²–10⁻³ S/m. A.C. electrical conductivity as a function of temperature follows an Arrhenius behaviour with an activation energy of 0.11 eV. The electrical conductivity of the same polycrystalline brucite material dried beforehand at 393 K (dry conditions) is lower by about 5–6 orders of magnitude at room temperature and possesses an activation energy of 0.8–0.9 eV which is close to that of protonic diffusion in (001) brucitic planes. Above ca. 873 K, a non-reversible conductivity jump is observed which is interpreted as a water transfer from mineral bulk to grain boundaries (i.e. partial dehydration). Cooling of such partially dehydrated sample shows electrical conductivities much higher than those of the initially dry sample by 4 orders of magnitude at 500 K. Furthermore, the corresponding activation energy is decreased by a factor of about four (i.e. 0.21 eV). Buffering of the sample at low water activity has been achieved by adding CaO or MgO, two hygroscopic compounds, to the starting material. Then, sample conductivities reached the lowest values encountered in this study with the activation energy of 1.1 eV. The strong dependency of the electrical conductivity with water activity highlights the importance of the latter parameter as a controlling factor of diffusion rates in natural processes where water availability and activity may vary grandly. Water exchange between mineral bulk and mineral boundary suggests that grain boundary can be treated as an independent phase in dehydroxylation reactions.  相似文献   

Polarimetry and Photometry of Comet C/2004 Q2 (Machholz)     

Sergey Velichko  Nikolai Kiselev  Feodor Velichko 《Earth, Moon, and Planets》2005,97(3-4):379-386

We present results of polarimetry and photometry of comet C/2004 Q2 (Machholz) obtained with the 0.7-m telescope of Institute of Astronomy at the Karazin Kharkiv National University on February 3 and 4, and March 4 and 14, 2005. The observations were carried out with a one-channel photoelectric photometer-polarimeter. The IHW continuum UC (λ3650/80 Å), BC (λ4845/65 Å), RC (λ6840/90 Å) and emission filters CN (λ3871/50 Å), C₃ (λ4060/70 Å), and C2 (λ5140/90 Å) were used. Degree of the comet polarization at phase angles ≈ 52° and ≈44° in the red continuum was close to that for so called dusty comets. The comet had a typical spectral gradient of polarization ΔP/Δλ=0.86% per 1000 Å. In the framework of the Haser model we have found the gas production rates Q of the CN, C₃ and C₂ species and the dust production rates Afρ on February 4 and March 14, 2005. The ratio log[Afρ (BC)/Q(CN)] was compared with data for other comets. The normalized spectral gradient of cometary dust S’(BC,RC) was 8.7%/1000 Å for February 4 and 17.0%/1000 Å for March 14. We conclude that comet C/2004 Q2 (Machholz) in many respects is a typical dusty comet.  相似文献   

Comparative Study Of The Dust Polarimetric Properties In Split And Normal Comets     

Kiselev  Nikolai  Jockers  Klaus  Rosenbush  Vera 《Earth, Moon, and Planets》2002,90(1-4):167-176

Our polarimetric database contains six comets, C/1975 V1 (West), 16P/Brooks 2,C/1988 A1 (Liller), D/1996 Q1 (Tabur), C/1999 S4 (LINEAR), and C/2001 A2(LINEAR), which can be related to the group of split comets. Comets West, S4(LINEAR) and A2 (LINEAR) were observed during splitting. We compare thepolarimetric measurements of the dust particles in these comets, sometimes togetherwith available photometric and colorimetric data, with those in normal comets. Weconclude that there is no significant evidence for differences of polarization betweentidally split comets (e.g., Brooks 2), dissipating comets (e.g., Tabur), non-tidally splitcomets (e.g., West) and normal comets. The total disintegration of Comet S4 (LINEAR), however, did produce significant changes in the observed properties of dust.  相似文献   

Spectrum of hot water in the 4750–13 000 cm⁻¹ wavenumber range (0.769–2.1 μm)     

Nikolai F. Zobov  Sergei V. Shirin  Roman I. Ovsyannikov  Oleg L. Polyansky  Robert J. Barber  Jonathan Tennyson  Peter F. Bernath  Michel Carleer  Reginald Colin  Pierre-François Coheur 《Monthly notices of the Royal Astronomical Society》2008,387(3):1093-1098

The high resolution laboratory spectrum of hot water vapour has been recorded in the 500–13 000 cm⁻¹ wavenumber range and we report on the analysis of the 4750–13 000 cm⁻¹ (0.769–2.1 μm) portion. The emission spectrum was recorded using an oxy-acetylene welding torch and a Fourier transform spectrometer. Line assignments in the laboratory spectrum as well as in an absorption spectrum of a sunspot umbra were made with the help of the BT2 line-list. Our torch spectrum is the first laboratory observation of the 9300 Å'steam bands' seen in M-stars and brown dwarfs.  相似文献